(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:
The electrochemical properties of σ-ethynyl complexes of chromium subgroup metals were studied by cyclic voltammetry and preparative-scale
electrolysis. The redox cycle of C5H5(CO)3CrC=CPh was shown to give the bis-carbyne complex (η5-C5H5)(CO)2Cr≡C-C(Ph)=C(Ph)-C-Cr(CO)2(η5-C5H5) formedvia the reductive Cβ−Cβ coupling of ethynyl moieties. The influence of the nature of the metal atom and the ligand environment on the course of this
reaction was considered.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1955–1958, October, 1998.