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The ring closure and rearrangement of 1-(2-amino)-benzoyl-1-methylhydrazones of β-dicarbonyl compounds: on the formation and crystal structure of 3a,9a-dihydro- -1,3,3a,9a-tetramethyl-4H-pyrazolo[3,4-b]quinolin-4-one
Authors:Melinda Gál  Ödön Fehér  Endre Tihanyi  Gyula Horváth  Gyula Jerkovich  Gyula Argay  Alajos Kálmán
Affiliation:Institute for Drug Research, H-1325-Budapest, P.O.B. 82., Hungary;Central Research Institute of Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, P.O.B., 17., Hungary
Abstract:The conversion of 1-(2-amino)-benzoyl-1-methylhydrazones of β-dicarbonyl compounds into heterocyclic derivatives yielded in addition to the already known type of product 2 further three novel pyrazole derivatives 3, 4 and 5. The structures of these products have been established by chemical and spectroscopic (MS) methods. The crystal structure of 5 has been determined by X-ray diffraction.
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