The ring closure and rearrangement of 1-(2-amino)-benzoyl-1-methylhydrazones of β-dicarbonyl compounds: on the formation and crystal structure of 3a,9a-dihydro- -1,3,3a,9a-tetramethyl-4H-pyrazolo[3,4-b]quinolin-4-one |
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Authors: | Melinda Gál Ödön Fehér Endre Tihanyi Gyula Horváth Gyula Jerkovich Gyula Argay Alajos Kálmán |
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Affiliation: | Institute for Drug Research, H-1325-Budapest, P.O.B. 82., Hungary;Central Research Institute of Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, P.O.B., 17., Hungary |
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Abstract: | The conversion of 1-(2-amino)-benzoyl-1-methylhydrazones of β-dicarbonyl compounds into heterocyclic derivatives yielded in addition to the already known type of product further three novel pyrazole derivatives , and . The structures of these products have been established by chemical and spectroscopic (MS) methods. The crystal structure of has been determined by X-ray diffraction. |
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