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Novel synthesis of 2,3-diarylbuta-1,3-dienes from 1,4-dimethoxybutyne-2
Authors:Yoshio Ishino  Ikuzo Nishiguchi  Fujio Takihira  Tsuneaki Hirashima
Institution:Osaka Municipal Technical Research Institute, 2-1-1, Ogimachi, Kita-Ku, Osaka, Japan 530
Abstract:It was found that 2,3-diarylbuta-1,3-dienes were readily obtained in good to excellent yields through the SN-2′ type substitution of 1,4-dimethoxybutyne-2 with aryl Grignard reagents in the presence of a copper(I) salt.
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