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Chiral and stereoselective total synthesis of (−)-deoxoprosopinine and (−)-deoxoprosophylline |
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| Authors: | Yutaka Saitoh Yoshihiko Moriyama Takeyoshi Takahashi Qui Khuong-Huu |
| Affiliation: | Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113, Japan;Institut de Chimie des Substances Naturelles, Centre National de la Recherche Scientifique, 91190 - Gif-sur-Yvette, France |
| Abstract: | (?)-Deoxoprosopinine and (?)-deoxoprosophylline were synthesized starting from -serine by a route involving the intramolecular aminomercuration of a chiral ?,ζ-unsaturated amine. |
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