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Silicon in synthesis: use of the highly nucleophilic trimethylsilyallyl anion for the synthesis of steroidal 17-spiro-γ-lactones |
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| Authors: | Ed Ehlinger Philip Magnus |
| Institution: | Evans Chemistry Laboratory Ohio State University 140 West 18th Avenue Columbus, Ohio 43210 U.S.A. |
| Abstract: | Trimethylsilylallylzinc chloride (M ZnCl) reacts with 17-ketosteroids to give adducts that can be converted into 17-spirolactones. |
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