Stereo- and regio-controlled aldol synthesis |
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Authors: | Isao Kuwajima Masahiro Kato Akio Mori |
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Institution: | Department of Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152 Japan |
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Abstract: | Treatment of (Z)-trimethylsilyl enol ethers with dibutylboryl trifluoromethanesulfonate followed by removal of trimethylsilyl triflate generated and addition of aldehydes affords the corresponding erythro aldols with almost complete stereo- and regio-selectivities. |
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