Aldol reaction of aluminium enolate resulting from 1,4-addition of Me<sub>2</sub>AlSPh to α,β-unsaturated carbonyl compound. A 1-acylethenyl anion equivalent期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Aldol reaction of aluminium enolate resulting from 1,4-addition of Me₂AlSPh to α,β-unsaturated carbonyl compound. A 1-acylethenyl anion equivalent

Authors:	Akira Itoh Shuji Ozawa Koichiro Oshima Hitosi Nozaki

Affiliation:	Department of Industrial Chemistry, Faculty of Engineering Kyoto University, Yoshida, Kyoto 606, Japan

Abstract:	Me₂AlSPh or Me₂AlSeMe adds to α,β-unsaturated carbonyl compounds in 1,4-fashion. The resulting aluminium enolates react with aldehydes effectively to afford the adducts of the title anion after formal PhSH (or MeSeH)-elimination.

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