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Aldol diastereoselection via zirconium enolates. Product-selective,enolate structure independent condensations.
Authors:D.A. Evans  L.R. McGee
Affiliation:Contribution No. 6258 from the Laboratories of Chemistry California Institute of Technology Pasadena, California 91125 U.S.A.
Abstract:Both(E)- and (Z)-zirconium enolates have been shown to undergo selective kinetic aldol condensation to give mainly erythro-β-hydroxy ketones, esters and amides.
Keywords:
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