A transannular reaction in an anionic oxy-cope system9 |
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Authors: | N Raju K Rajagopalan S Swaminathan JN Shoolery |
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Institution: | Department of Organic Chemistry, University of Madras, A.C. College Campus, Madras-600 025, India;Varian Instrument Group, Palo Alto, California, 94303, U.S.A. |
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Abstract: | The carbinol is found to rearrange to the bicyclo (2,2,2) octane derivative in the presence of base; the rearrangement involves a transannular reaction in a ten membered ring resulting from an Oxy-Cope system. |
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