A (π2 + π2) photocycloaddition reaction as a facile route to angularly substituted cis-hydrindanes and cis-decalanes |
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| Authors: | M Van Audenhove D De Keukeleire M Vandewalle |
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| Institution: | Laboratory of Organic Chemistry, State University of Ghent, Krijgslaan, 271 (S.4), B-9000 Gent Belgium |
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| Abstract: | The photochemical addition of 1,2-bis(trimethylsiloxy) cyclobutene to, respectively, 2-cyclopentenones and 2-cyclohexenones represents a novel and facile entry into angularly substituted bicyclo4.3.0]nona-2,5-diones and bicyclo-4.4.0]deca-2,5-diones. |
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