Synthesis of β=iodo-<span class="math"><math><mtext>t</mtext></math></span>-butyl and methyl ethers from the reaction of alkenes with <span class="math"><math><mtext>t</mtext></math></span>-butyl and methyl hypoiodites期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Synthesis of β=iodo- $t$ -butyl and methyl ethers from the reaction of alkenes with $t$ -butyl and methyl hypoiodites

Authors:	Stephen A Glover André Goosen

Institution:	Department of Chemistry, University of Port Elizabeth, P.O. Box 1600, Port Elizabeth 6000, South Africa

Abstract:	$t$ -Butyl or methyl hypoiodite, generated from potassium t-butoxide or sodium methoxide and iodine monochloride, react with olefins via a bridged iodonium ion intermediate giving the $trans$ -vicinal iodo - $t$ -butyl or -methyl ethers.

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