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Proposal of a symmetry rule for β,γ-unsaturated ketones |
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| Authors: | Hiroko Kuritani Keiji Shingu Masazumi Nakagawa |
| Affiliation: | Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka, 560 Japan |
| Abstract: | A symmetry rule for the sign of Cotton effect of β,γ-unsaturated ketnoes in n → π* region has been proposed and this rule can correctly predict the sign of c.d. even for the ketones to which the generalized octant rule could not be applied. |
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