A facile access to α-phenylselenenyl carbonyl compounds by electrochemical oxidation |
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| Authors: | Sigeru Torii Kenji Uneyama Ko Handa |
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| Institution: | Department of Industrial Chemistry, School of Engineering, Okayama University, Okayam 700, Japan |
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| Abstract: | A novel α-phenylselenenylation of carbonyl compounds has been performed by electrolysis of a solution of ketones, diphenyl diselenide, tetraethylammonium bromide, and magnesium bromide in polar solvents (MeOH, AcOH, MeCN). The electrolysis enables us to prepare the desired seleno-carbonyl compounds without employing strong bases and the activated selenenyl reagents PhSeX. |
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