Bis(triphenylphosphine)copper (I) tetrahydroborate in the reduction of -toluenesulphonylhydrazones and 2,4,6-triisopropylbenzenesulphonyl hydrazones (trisyl hdyrazones) to alkanes |
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Authors: | GWJ Fleet PJC Harding MJ Whitcombe |
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Institution: | Dyson Perrins Laboratory, Oxford University South Parks road, Oxford, U.K. |
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Abstract: | Saturated ketones and aldehydes are converted via their -toluenesulphonyl hydrazones to the corresponding alkanes by treatment with bis(triphenylphosphine) copper (I) tetrahydroborate; trisylhydrazones give moderate yields of alkanes at room temperature on treatment with bis(triphenylphosphine)copper (I) tetrahydroborate. |
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