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X=Y-ZH systems as potential 1,3-dipoles. The stereochemistry and regiochemistry of cycloaddition reactions of imines of α-amino-acid esters.
Authors:Ronald Grigg  James Kemp
Institution:(Chemistry Department, Queen''s University, Belfast BT9 5AG, Northern Ireland
Abstract:The stereochemistry and regiochemistry of cycloadditions of α-amino acid ester imines is dependent both on imine structure and on the reactivity of the dipolarophile. Phenylglycine imines undergo competing dipole stereomutation and cycloaddition with some dipolarophiles.
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