Stereoselective photosolvolyses of -acetoxynitro-adducts of -xylene |
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Authors: | Hideto Shosenji Kensaku Esaki Kimiho Yamada |
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Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kumamoto University, Kumamoto 860, Japan |
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Abstract: | Diastereoisomers of 1,4-dimethyl-4-nitro-2,5-cyclohexadienyl acetate exchanged acetoxyls for alkoxyls on irradiation in alcohols to give the diastereoisomers of alkyl, 1,4-dimethyl-4-nitro-2,5-cyclohexadienyl ethers in isomer ratios of 70:30, whereas the irradiation in pentane yielded -xylene. |
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