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Oxydes d'allenes VI (1). migration-1,4 de fonction lors de l'oxydation selective de derives d'alcools α-alleniques. Synthese de dienones conjuguees. |
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| Authors: | M. Bertrand J-P Dulcere G. Gil |
| Abstract: | The oxydation of α-allenic acetates affords conjugated dienones whereas α-allenic trimethylsilyl ethers give rise to silyl ethers of unsaturated α-cetols. A ?1,4 migration of the function is involved. |
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