Asymmetric hydrosilylation of olefins catalyzed by a chiral ferrocenylphosphine-palladium complex. Asymmetric synthesis of optically active alcohols and bromides from olefins |
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| Authors: | Tamio Hayashi Kohei Tamao Yoshio Katsuro Ichiro Nakae Makoto Kumada |
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| Institution: | Department of Synthetic Chemistry, Kyoto University, Kyoto 606, Japan |
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| Abstract: | Optically active norbornyl and 1-phenylethyl alcohols and bromides were obtained, respectively, from norbornyl- and 1-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-palladium complex followed by treatment with potassium fluoride. |
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