Preparation and synthetic use of the zerovalent nickel complex by electrochemical reduction |
| |
Authors: | Miwako Mori Yasuko Hashimoto Yoshio Ban |
| |
Institution: | Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060, Japan |
| |
Abstract: | The generation of Ni(PPh3)4 by electrochemical reduction was carried out in a divided cell containing NiCl2(PPh3)4, PPh3 and n-Bu4NBr in DMF with a lead plate as cathode and a platinum plate as anode under the stream of argon at 60°. Using this Ni(PPh3)4, biphenyls and the heterocyclic compounds were synthesized in fairly good yields. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |