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Enantioselectively catalyzed oxidation of 3,4-dihydroxy-l-phenylalanine by N-lauroyl L or D-histidine-Cu(II) complex in CTABr micelles.
Authors:Kimiho Yamada  Hideto Shosenji  Yonejiro Otsubo  Shuji Ono
Affiliation:Department of Synthetic Chemistry, Faculty of Engineering, Kumamoto University, Kumamoto 860, Japan
Abstract:In order to investigate the enzyme model reaction the oxidation of 3,4-dihydihydroxy-L-phenylalanine(L-DOPA) was carried out using optically active catalyst, N-lauroyl L or D-histidine-Cu(II) complex(L or D-LauHis-Cu(II)), showing appreciable enantioselectivity in the presence of the mixed micelles with CTABr.
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