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A new,facile synthesis of the 3-methyl-2(5H)-furanoid structural unit from ketones |
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| Authors: | Seppo I Pennanen |
| Institution: | Department of Chemistry, Helsinki University of Technology, 02150, Otaniemi,Finland. |
| Abstract: | The 3-methyl-2(5H)-furanoid structural unit is prepared from ketones via 1,4-rearrangement of siloxyalkenes on peroxidation and via oxetene rearrangement of 1-diethylaminopropyne in 53–58% overall yield. |
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