Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters |
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| Authors: | Ilhyong Ryu Koichi Matsumoto Masato Ando Shinji Murai Noboru Sonoda |
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| Affiliation: | Department of Petroleum Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565, Japan |
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| Abstract: | Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields. |
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