Dinuclear cage-like metalloorganosiloxane containing CrIII ions |
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| Authors: | A N Bilyachenko A A Korlyukov M M Levitskii B G Zavin M Yu Antipin O A Filippov V I Tsupreva |
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| Institution: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
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| Abstract: | Cage-like chromium sodium phenylsiloxane (PhSiO1.5)12(CrO1.5)2(NaO0.5)6·3BuOH·9EtOH·2H2O containing two CrIII ions was prepared for the first time by the exchange reaction of sodium phenylsilanolate with CrCl3. The coordination sphere of the metal atom is filled by silanolate anions and water molecules located in the inner cavity of the cage. The structure of this compound was established by X-ray diffraction. |
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