X-ray absorption near edge structure as a source of structural information |
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Authors: | A. V. Soldatov |
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Affiliation: | (1) I. Ya. Postovsky Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Ekaterinburg;(2) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk |
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Abstract: | N-(2-Hydroxyethyl)-β-alaninatonickel(II) was synthesized by the interaction of basic nickel carbonate with N-(2-hydroxyethyl)-β-alanine. The structures of the chelating agent and its nickel complex were studied by single crystal X-ray diffraction. In the synthesized compound, the nickel ion lies at the center of an octahedron of the N and 2O donor atoms of two tridentate ligands, each ligand having a meridional conformation. The ligands around the central atom are arranged in perpendicular planes. This coordination of two ligands yields two stereoisomers, whose cocrystallization affords a racemate. |
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Keywords: | crystal structure N-(2-hydroxyethyl)-β -alaninatonickel(II) stereoisomers racemic mixture |
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