Synthesis and structural characterization of the first metal organic thallium antimonide |
| |
| Authors: | Schulz Stephan Thomas Florian Nieger Martin |
| |
| Institution: | Department Chemie, Universit?t Paderborn, Warburger Strasse 100, J6.214, 33098 Paderborn, Germany. stephan.schulz@upb.de |
| |
| Abstract: | The first metal organic thallium antimonide, the heterocycle Me2TlSb(SiMe3)2]3, was synthesized by reaction of Me2AlSb(SiMe3)2]3 with the Lewis acid-base adduct dmap-TlMe3 (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle Me2TlBi(SiMe3)2]3 couldn't be isolated due to its limited thermal stability in solution. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
