| 电子能谱法研究改性的聚丙烯纤维性能与结构关系 |
| |
| 引用本文： | 张瑞峰 金杰. 电子能谱法研究改性的聚丙烯纤维性能与结构关系[J]. 光谱实验室, 1993, 10(6): 22-26 |
| |
| 作者姓名： | 张瑞峰 金杰 |
| |
| 作者单位： | 中国科学院长春应用化学研究所，中国科学院长春应用化学研究所，中国科学院广州化学研究所，中国科学院广州化学研究所，中国科学院广州化学研究所 吉林省长春市斯大林大街109号，130022，吉林省长春市斯大林大街109号，130022，广州市，510650，广州市，510650，广州市，510650 |
| |
| 摘 要： | 本文讨论了聚丙烯纤维(PPF)在Ar、N_2、O_2和空气等离子体作用时,改变时间和功率对PPF表面进行等离子体处理,发现处理后纤维的吸湿性变化很大,回潮率是未处理样品的120-400%,染色性能从5级提高到1级标准。这一变化的光电子能谱法研究结果表明:PPF表面的结构发生较大变化。表面大量引入含O、N极性基团。经谱图拟合可知,这些基团是亲水性的极性结构,应归属于C-OH、C=O、COOH、C-NH_2和CONH_2基团。
|
| 关 键 词： | 聚丙烯纤维 XPS研究 等离子体改性 PPF结构 |
Relationship of Characterization and structure of polypropylene Fibre by Photoelectron Spectroscopy |
| |
| Zhang Ruifeng and Li Xinglin,Changchun Institute of Applied Chemistry,Academia Sinica,No. Sidalindajie,Changchun ,P. R. ChinaAn Jie,Liu Xueshu and Yao Yaoguang,Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou ,P. R. China. Relationship of Characterization and structure of polypropylene Fibre by Photoelectron Spectroscopy[J]. Chinese Journal of Spectroscopy Laboratory, 1993, 10(6): 22-26 |
| |
| Authors: | Zhang Ruifeng Li Xinglin Changchun Institute of Applied Chemistry Academia Sinica No. Sidalindajie Changchun P. R. ChinaAn Jie Liu Xueshu Yao Yaoguang Guangzhou Institute of Chemistry Academia Sinica Guangzhou P. R. China |
| |
| Affiliation: | Zhang Ruifeng and Li Xinglin,Changchun Institute of Applied Chemistry,Academia Sinica,No. 109 Sidalindajie,Changchun 130022,P. R. ChinaAn Jie,Liu Xueshu and Yao Yaoguang,Guangzhou Institute of Chemistry,Academia Sinica,Guangzhou 510650,P. R. China |
| |
| Abstract: | In this report, the moisture absorption, dyeability, mechanical pro- peries and weightlessness of plasma-treated PPF are investigated. The composition, structure and states of the PPF surface are characterized by photoelectron spectroscopy. The results show that moisture absorption of the plasmatreated PPF is increased by 120-400% and the dyeability is improved in standards from 5th to 1th grade approximately. By using curve fitting method, we have found that functional groups, such as C-OH, C=O, COOH, C-NH_2, CONH_2 were introduced into surface of polypropylene fibre. |
| |
| Keywords: | Polypropylene Fibre XPS Study Plasma Treatment PPF Structure |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
