A new route to mer-Tricarbonyls of manganese(I) containing N-donor chelate ligands |
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| Institution: | 1. Institute of Aquatic Science and Technology, National Kaohsiung University of Science and Technology, Kaohsiung, Taiwan;2. Department of Tropical Agriculture and International Cooperation, National Pingtung University of Science and Technology, Pingtung, Taiwan;3. Pingtung County Ping Rong High School, Pingtung, Taiwan;4. Department of Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan;5. Department and Graduate Institute of Aquaculture, National Kaohsiung University of Science and Technology, Kaohsiung, Taiwan;6. Tungkang Biotechnology Research Center, Fisheries Research Institute, Taiwan;7. Institute of Aquatic Science and Technology, College of Hydrosphere, National Kaohsiung University of Science and Technology, Kaohsiung, Taiwan;8. Department of Aquaculture, National Pingtung University of Science and Technology, Pingtung, 91201, Taiwan;1. Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 106, Taiwan;2. Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan;1. Key Laboratory of Clay Mineral Applied Research of Gansu Province, Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, PR China;2. University of Chinese Academy of Sciences, Beijing 100049, PR China;3. Center of Xuyi Palygorskite Applied Technology, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Xuyi, 211700, PR China;1. School of Cancer and Pharmaceutical Sciences, King’s College London, London SE1 1DB, United Kingdom;2. Research and Development Institute, National Infections Service, Porton Down, Public Health England, Salisbury SP4 0JG, Wiltshire, United Kingdom |
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| Abstract: | It has been shown that new mer-tricarbonyls mer-Mn(CO)3L(tmed)]ClO4, (tmed = N,N,N′,N′-tetramethylethylenediamine, L = P(OMe)3, P(OEt)3, P(O-iPr)3) can be readily obtained from the reaction between fac-Mn(CO)3(tmed)Br, AgClO4, and L at room temperature, whereas at 0°C fac-isomers are produced. The opposite is the case for L = CN-t-Bu; mer-Mn(CO)3(CN-t-Bu)(tmed)]ClO4 is observed at 0°C, and the fac-isomer is stable at 25°C. |
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