Synthetic and electrochemical studies on alkynyl complexes of iron and ruthenium |
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| Institution: | 1. Department of Chemistry and Physics, Indiana State University, Terre Haute, IN 47809 USA;2. Theoretical Chemistry Institute and Department of Chemistry, University of Wisconsin-Madison, WI 53706 USA;1. Global Institute for Water Security, University of Saskatchewan, Saskatoon, Saskatchewan, Canada;2. School of Environment and Sustainability, University of Saskatchewan, Saskatoon, Saskatchewan, Canada;3. Department of Civil, Geological, and Environmental Engineering, University of Saskatchewan, Saskatoon, Saskatchewan, Canada;4. Department of Hydrology & Atmospheric Sciences, The University of Arizona, Tucson, AZ, USA;1. Department of Pharmacology & Toxicology, University of Toronto, Toronto, ON, Canada;2. Campbell Family Mental Health Research Institute, CAMH, Toronto, Canada;3. Clinical Pharmacology Research Program, Division of Cardiology, Department of Medicine, University of California, San Francisco, CA, USA;4. Center for Alcohol and Addiction Studies, Department of Behavioral and Social Sciences, Brown University School of Public Health, Department of Medicine, Warren Alpert Medical School, Providence, RI, USA;5. Department of Population Health, University of Kansas Medical School, Kansas City, KS, USA;6. Norris Comprehensive Cancer Center, University of Southern California, Los Angeles, USA;7. Institute of Medical Sciences, University of Toronto, Toronto, ON, Canada;8. Center for Tobacco Control Research and Education, University of California, San Francisco, CA, USA;9. Addictions Division, CAMH and Department of Psychiatry, University of Toronto, Toronto, ON, Canada |
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| Abstract: | Cyclic voltammetric studies on a series of alkynyl complexes M(CCR)L2(η- C5R′5)] (M = Fe or Ru; R = Ph, Bun or But; L = CO or P-donor ligand; R′ = H or Me) reveal a one-electron oxidation at a glassy carbon electrode in dichloromethane. The chemical reversibility of the oxidation process is dependent upon all four variables (M, L, R and W) considered in this investigation. |
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