Dodecacarbonyltriruthenium catalyzed one-to-one addition of N-substituted formamide to olefins期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Dodecacarbonyltriruthenium catalyzed one-to-one addition of N-substituted formamide to olefins

Institution:	1. Organic Chemistry Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695 019, India;2. Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India;3. Department of Chemistry, University of Jyväskylä, Finland;4. Inorganic Chemistry Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum, 695019, India;1. Toyo College of Food Technology, 4-23-2 Minami-hanayashiki, Kawanishi-shi, Hyogo 666-0026, Japan;2. Research Organization for the 21st Century, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan;3. Graduate School of Life and Environmental Sciences, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan;1. Laboratory for Medicinal Chemistry and Natural Products, Lebanese University, Faculty of Sciences (1) and PRASE-EDST, Hadath, Beirut, Lebanon;2. Université de Rennes 1, Institut des Sciences Chimiques, CNRS UMR 6226, Avenue du Général Leclerc, 35042 Rennes Cedex, France

Abstract:	Dodecacarbonyltriruthenium (Ru₃(CO)₁₂) showed high catalytic activity for the first one-to-one addition of N-substituted formamides to both terminal and internal olefins at 180-200°C under a carbon monoxide pressure of 20 kg cm⁻². The addition of N-metylformamide to cyclopentene afforded N-methylcyclopentanecarboxamide in 90% yield.

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