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A simple convenient method for the generation of diborane from NaBH4 and I2
Affiliation:1. University of Oulu, Research Unit of Sustainable Chemistry, P.O. Box 3000, FIN-90014 Oulu, Finland;2. Centria University of Applied Sciences, FI-67100 Kokkola, Finland;3. Department of Chemical Engineering, COMSATS Institute of Information Technology, Lahore, Pakistan;4. Centre of Research in Ionic Liquids, Universiti Teknologi PETRONAS, Bandar Seri Iskandar 32610, Perak, Malaysia;5. Univ. Savoie Mont Blanc, LCME, F-73000 Chambéry, France;6. Department of Chemistry, Faculty of Natural Science and Technology, Norwegian University of Science and Technology, 7491 Trondheim, Norway
Abstract:Treatment of NaBH4 with I2 in diglyme yields diborane which can be utilized conveniently for the preparation of a borane-N,N-diethylaniline complex and other borane-Lewis base complexes.
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