Vibrational and 1H NMR spectra of N-(2-pyridyl)-thioformamide and N-(2-pyridyl)thioacetamide |
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Affiliation: | 1. Department of Chemistry, Jadavpur University, Kolkata 700032, India;2. Department of Chemistry, Bagnan College, Howrah, WB 711303, India;3. Department of Signal Transduction and Biogenis Amines (STBA), Chittaranjan National Cancer Institute, Kolkata 700026, India |
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Abstract: | The Raman and infrared spectra of N-(2-pyridyl)thioformamide and N-(2-pyridyl)-thioacetamide have been measured. The assignment of the bands is aided by the complete normal coordinate treatment for all the vibrations of N-(2-pyridyl)thioformamide and its N-deuterated molecule using a Urey—Bradley force function for the in-plane vibrations and a valence force function for the out of plane vibrations. Variable temperature 1H NMR study of the two pyridylthionamides has also been performed. It is inferred that while N-(2-pyridyl)thioformamide favours a cis —CSNH— group, the other compound favours a trans —CSNH— grouping at ambient temperature. |
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