Trimethylsilylsubstituierte Cyclopentadienylindium(I) Verbindungen; Synthese and Eigenschaften |
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| Institution: | 1. International Islamic University, H-10, Islamabad, Pakistan;2. Pakistan Institute of Nuclear Science & Technology, Nilore Islamabad, Pakistan;3. University of Engineering & Technology, Lahore, Pakistan;4. University of the Punjab, Lahore, Pakistan;1. Arnold and Marie Schwartz College of Pharmacy and Health Sciences, Long Island University, Brooklyn NY-11201, USA;2. Departments of Medicine and Pharmacological Sciences, Icahn School of Medicine at Mount Sinai, New York, NY 10029, USA;3. Department of Surgery, Weill Cornell Medical College of Cornell University, New York, NY 10065, USA |
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| Abstract: | Reaction of indium(I) chloride with trimethylsilylated cyclopentadienyllithium species yields the air- and moisture-sensitive cyclopentadienylindium complexes In(Me3Si)C5H4] (1), In(Me3Si)2C5H3] (2) and In(Me3Si)3C5H2] (3), which are volatile and easily soluble in nonpolar solvents. Compound 1 crystallizes as a chain polymer. |
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