Photochemisch initiierte oxidative spaltung von [C5H5Mo(CO)3]2; ein einfacher zugang zu kationischen komplexen des typs [C5H5Mo(CO)2L2]BF4 |
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| Affiliation: | Fachbereich 6-Anorganische Chemie-der Universität (GH) Duisburg, Lotharstrasse 1, D-4100 Duisburg 1 B.R.D.;Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Taiyuan, 030031, China;Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, PR China;Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education & School of Chemistry and Materials Science of Shanxi Normal University, TaiYuan, 030032, China |
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| Abstract: | The MoMo bond in [C5H5Mo(CO)3]2 is cleaved by ferricenium cations in the presence of additional Group V ligands under photochemical radiation (λmax > 300 nm). The mononuclear cationic complexes [C5H5Mo(CO)2L2]BF4 (L = E(C6H5)3, E = P, As, Sb, Bi; L2 = [(C6H5)2PCH2]2) are obtained in high yield. |
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