Structural investigations of alumino-metalloaminocarbene complexes |
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| Institution: | 1. Department of Chemistry, Warsaw University, Pasteura 1, 02-093 Warsaw, Poland;2. Department of Theoretical Chemistry, University of Białystok, Hurtowa 1, 15-399 Białystok, Poland;3. Department of Theoretical and Structural Chemistry, Faculty of Chemistry, University of Łódź, Pomorska 163/165, 90-236 Łódź, Poland;1. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, ON M5S 3H6, Canada;1. Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, 615-8510, Japan;2. Fukui Institute for Fundamental Chemistry, Kyoto University, Takano-Nishihiraki-cho 34-4, Sakyo-ku, Kyoto, 606-8103, Japan;3. Element Strategy Initiative for Catalysts and Batteries, Kyoto University, Goryo-Ohara 1-30, Nishikyo-ku, Kyoto, 615-8245, Japan;1. Technical University of Munich, School of Natural Sciences, Department of Chemistry and Catalysis Research Center, Molecular Catalysis, Lichtenbergstraße 4, 85748 Garching, Germany;2. Georg-August-Universität Göttingen, Institut für Anorganische Chemie, Tammannstraße 4, 37077 Göttingen, Germany |
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| Abstract: | Al(NMe2)3]2 combines with Fe(CO)5 and Mn2(CO)10 forming bimetallic compounds Fe2(CO)8C(NMe2)OAl(NMe2)2]2 and Mn2(CO)9C(NMe2)OAl2-(NMe2)5]. X-ray diffraction analyses reveal the formation of aluminometallocarbene compounds with central connectivities, MCNMe2)]OAl(NMe2)(μ-NMe2)2]. |
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