Studies on the interaction of peroxy radicals with transition metals complexes: I. Effect of 2-cyano-2-propyl and 2-cyano-2-propyl peroxy radicals on cobaloximes |
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| Affiliation: | 1. Medical Research Center Oulu, Research Unit of Biomedicine, University of Oulu, FI-90014 Oulu, Finland;2. Copenhagen Center for Glycomics, Department of Cellular and Molecular Medicine, Faculty of Health Sciences, University of Copenhagen, DK-2200 Copenhagen N, Denmark;1. Department of Chemistry, University of Alberta, Edmonton, AB, Canada;2. University of Minnesota, Minneapolis, MN, United States;3. 3M China, Shanghai, China |
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| Abstract: | Reactions of CH3Co(DH)2py (1) and [Co(DH)2py]2 (2) with (CH3)2(CN)C (r) and (CH3)2(CN)COO (rO2) radicals were investigated. At 60°C, reaction or r with (1) results in non-homogeneous ligand decomposition, whereas for 2, complex (CH3)2CNCCo(DH)2py (6) and a precipitate are formed. Ligand decomposition also took place at 60°C when the reaction of rO2 radicals with 1 and 2 was investigated. However, the same reaction with rO2 radicals at −10°C, yielded two complexes, CH3OOCo(DH)2py (3) and Co(DH)2py (4) with 1, and complex 6 for the reaction of rO2 with 2. |
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