Crystal and molecular structure of bis[tetracarbonyldiphenylphosphidomanganese(0)] |
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| Institution: | 1. Sea Mammal Research Unit, Scottish Oceans Institute, University of St Andrews, St Andrews KY16 8LB, Scotland, UK;2. Oceans Initiative, Pearse Island, BC V0N 1A0, Canada;3. Centre for Marine Science & Technology, Curtin University, Perth, WA 6102, Australia;4. Bioacoustics Research Program, Cornell University, 159 Sapsucker Woods Rd., Ithaca, NY 14850, USA |
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| Abstract: | The crystal structure of bistetracarbonyldiphenylphosphidomanganese(0)] has been determined by an X-ray diffraction study. The complex crystallizes in the monoclinic space group P21/n with four molecules in a unit cell of dimensions, a 15.714(4), b 16.446(5), c 12.016(4) Å, and β 101.25(2)°. The molecule has approximately centrosymmetric bi-octahedral D2h structure. Each manganese atom is bonded to two phosphorus atoms of μ-diphenylphosphide groups and four carbonyl carbon atoms. The separation of the manganese atoms is 3.690(1) Å. |
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