Optical emission spectrum of the NO2+ dication |
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| Affiliation: | 1. J. Heyrovsky Institute of Physical Chemistry, Czech Academy of Sciences, Dolejškova 2155/3, 18200, Prague 8, Czech Republic;2. Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 78/7, 11519, Prague 1, Czech Republic;3. Faculty of Mathematical and Physical Sciences, University College London, Gower Street, London WC1E 6BT, United Kingdom;1. Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, UK |
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| Abstract: | We recorded and rotationally analyzed a new emission band at 2563 Å obtained from a low-pressure, hot cathode and magnetically confined electric discharge through pure NO vapor. The available experimental data from photoion-fluorescence photon coincidence and translational energy loss spectroscopy, in conjunction with ab initio calculation, allowed assignment of the new band to the B2Σ+-X2Σ+ (0, 0) transition of the NO2+ ion. |
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