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Molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone |
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| Authors: | P. N. Bourosh M. D. Revenko M. Gdaniec E. F. Stratulat Yu. A. Simonov |
| Affiliation: | (1) Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Republic of Moldova;(2) Moldova State University, Chisinau, Republic of Moldova;(3) Chemical Faculty, A. Mickiewicz University, Poznań, Poland |
| Abstract: | The molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone is determined. The thiosemicarbazide fragment has cis-arrangement of terminal nitrogen atoms relative to the central N-C bond. The structure is based on a centrosymmetric dimer formed by hydrogen bonds between NH groups and sulfur atoms of thiosemicarbazide fragments of the neighboring molecules. In the crystal, the dimers are joined with each other through a system of hydrogen bonds and intermolecular π-π interactions. |
| Keywords: | quinoline-2-aldehyde thiosemicarbazone synthesis structure configuration crystal structure |
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