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RADICAL POLYMERIZATION OF N, N-DI(2-2''''-METHYL-ACRYLOYLOXY-PROPYL)-PARA-TOLUIDINE FUNCTIONAL MONOMER
引用本文:丘坤元,傅杰. RADICAL POLYMERIZATION OF N, N-DI(2-2''''-METHYL-ACRYLOYLOXY-PROPYL)-PARA-TOLUIDINE FUNCTIONAL MONOMER[J]. 高分子科学, 1989, 0(3): 258-265
作者姓名:丘坤元  傅杰
作者单位:Department of Chemistry,Peking University,Beijing,Department of Chemistry,Peking University,Beijing
摘    要:Functional monomer (MP)_2PT having tertiary aromatic amino group was systhesized from the reaction of N, N-di (2-hydroxypropyl)-p-toluidine with 2-methyl acryloyl chloride. In the presence of organic peroxide, the radical polymerization of (MP)_2PT in toluene took place. The kinetics of (MP)_2PT polymerization and the ESR spectra of LPO-(MP)2PT-MNP systems were determined respectively.

关 键 词:Functional monomer   N   N-di(2-2′-methylacryloyloxy-propyl )-p-toluidine   Synthesis   Radical polymerization   Kinetics of polymerization   ESR study on the radical intermediates.
收稿时间:1988-07-12

RADICAL POLYMERIZATION OF N, N-DI(2-2''''-METHYL-ACRYLOYLOXY-PROPYL)-PARA-TOLUIDINE FUNCTIONAL MONOMER
QIU Kunyuan,FU Jie. RADICAL POLYMERIZATION OF N, N-DI(2-2''''-METHYL-ACRYLOYLOXY-PROPYL)-PARA-TOLUIDINE FUNCTIONAL MONOMER[J]. Chinese Journal of Polymer Science, 1989, 0(3): 258-265
Authors:QIU Kunyuan  FU Jie
Affiliation:Department of Chemistry; Peking University; Beijing
Abstract:Functional monomer (MP)_2PT having tertiary aromatic amino group was systhesized from the reaction of N, N-di (2-hydroxypropyl)-p-toluidine with 2-methyl acryloyl chloride. In the presence of organic peroxide, the radical polymerization of (MP)_2PT in toluene took place. The kinetics of (MP)_2PT polymerization and the ESR spectra of LPO-(MP)2PT-MNP systems were determined respectively.
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