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Heterocycles. XXVI. A total synthesis of optically pure (+)-catechin pentaacetate
Authors:Mieko Urano  Hitoshi Kagawa  Yoshihiro Harigaya  Shaoshun Li  Masayuki Onda
Abstract:A total synthesis of optically pure (+)-catechin pentaacetate has been established using the (-)-chalcon epoxide (100% ee) derived from 3,4,2′,4′,6′-pentakis(methoxymethoxy)chalcon as the starting material. The optical purity of the product is confirmed by 1H nmr analysis in the presence of a shift reagent.
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