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Ozone-based sulfur chemiluminescence detection: Its applicability to gas,supercritical fluid,and high performance liquid chromatography
Authors:Angela L. Howard  Larry T. Taylor
Abstract:The sensitive detection of sulfur-containing analytes is of interest in many industrial applications; selective detection is also desirable since these compounds are usually present at trace levels in difficult matrixes. The purpose of this article is to review the use of the Sievers® ozone-based sulfur chemiluminescence detector, and its coupling with gas chromatography, supercritical fluid chromatography, and high performance liquid chromatography. Detection limits, linearity, response factors, and selectivity are discussed for each of these techniques. Critical operational parameters for the SCD are also described. The use of other sulfur selective detectors for SFC and HPLC is also briefly summarized.
Keywords:GC  Supercritical fluid chromatography  (SFC)  Packed capillary HPLC  Sulfur-selective detection  Ozone-based sulfur chemiluminescence detection
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