Abstract: | In a recent work, Csvinszky formulated a variational density-functional approach for the investigation of the spatial generalization of Kato's theorem by March. In the previous work, a 10-electron model system (filled K and L shells) was considered. In the present work, the investigation is extended to two other cases: a 28-electron model system (filled K, L, and M shells) and a 60-electron model system (filled K, L, M, and N shells). As in the previous work, several expressions are adapted for the kinetic-energy functional of the electrons and the intriguing question of identifying the “best” kinetic-energy functional is raised and discussed. |