Radiation removal of lead and cadmium complexed with ethylenediamine tetraacetic ACID from aqueous solutions |
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Authors: | B Drtinová M Pospí?il V Mú?ka V ?uba |
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Institution: | (1) Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Břehová 7, 115 19 Prague 1, Czech Republic;(2) Centre for Radiochemistry and Radiation Chemistry, Czech Technical University in Prague, Břehová 7, 115 19 Prague 1, Czech Republic |
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Abstract: | The removal of lead (100 mg/L) and cadmium (27 mg/L) complexed with ethylenediamine tetraacetic acid (EDTA) in presence of
different scavengers has been investigated. The experiments show that in acidic solutions, the EDTA complexed lead may be
reduced at a dose of 40 kGy up to 97% without the addition of typical OH radical scavengers such as Na(K) formate. The addition
of OH radical scavengers as 1×10−3 mol/L HCOOK, 2×10−3 mol/L carbonate or 2×10−3 mol/L bicarbonate (wide range of pH) results in no further improvement. The bubbling of the solution with nitrogen or oxygen
also exhibits no positive effect. On the contrary, saturation with nitrous oxide in the presence of scavengers has a modest
positive influence, whereas in the system which is scavenger-free, high negative effect (30 %) was observed. The presence
of nitrate (e
aq
−
scavenger) appears to be important for an effective reduction of complexed lead. The efficient removal of cadmium complexed
with EDTA proceeds up to 96 % at a dose of 40 kGy with an addition of 5×10−3 mol/L of carbonate as the OH radical scavenger and simultaneously pH buffer (pH 10.5). After irradiation, the cadmium is
present in the final form of CdCO3. |
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Keywords: | |
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