Thermodynamical Phase Equilibrium of Iron Nitrides at Low Temperatures |
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作者姓名: | 雷明凯 王兴军 |
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作者单位: | [1]SurfaceEngineeringLaboratory,DepartmentofMaterialsEngineering,DalianUniversityofTechnology,Dalian116024 [2]SurfaceEngineeringLaboratory,DepartmentofMaterialsEngineering,DalianUniversityofTechnology,Dalia |
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摘 要: | The presence of α-Fe(N),γ‘-Fe4N and ε-Fe2N1-x phases and the phase equilibrium between αFe(N) and γ′-Fe4N,and γ′-Fe4N and ε-Fe2N1-x have been studied at low temperatures below 350℃ ,according to the binary Fe-N phase diagram calculated using the sublattice-compound energy model,The α-Fe(N),γ′-Fe4N and ε-Fe2N1-x phases would be thermodynamically stable at the low temperatures.Thermodynamic phase equilibrium of the iron nitrides is supproted by the experimental results,explaining the phase formation and its stability in the Fe-N system at low temperatures.
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关 键 词: | 氮化铁 热力学平衡相 实验 |
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