| 单宁酸与苯酚在复合功能树脂上的竞争吸附研究 |
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| 引用本文： | 陆朝阳,姜笔存,李爱民,王旭,马依菲,沈晓鹏.单宁酸与苯酚在复合功能树脂上的竞争吸附研究[J].化学学报,2010,68(5):437-442. |
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| 作者姓名： | 陆朝阳 姜笔存 李爱民 王旭 马依菲 沈晓鹏 |
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| 作者单位： | 1. 南京大学环境学院,污染控制与资源化研究国家重点实验室,南京,210093;江苏南大戈德环保科技有限公司,国家环境保护有机化工废水治理与资源化工程技术中心,南京,210046
2. 南京大学环境学院,污染控制与资源化研究国家重点实验室,南京,210093 |
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| 基金项目： | 国家杰出青年基金(No.50825802);;国家自然科学基金(No.50578088);;国家“863”高技术基金(No.2006AA06Z383)资助项目 |
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| 摘 要： | 研究了水源水和生化尾水中的代表性模拟背景污染物单宁酸和代表性有机毒物苯酚之间的竞争吸附行为,开展了单组分、同时竞争吸附和预负载竞争吸附实验.研究表明,单宁酸对苯酚在复合功能树脂上的吸附有显著削弱作用.竞争吸附机理包括孔堵塞和吸附质间作用:单宁酸对树脂上微孔的堵塞,减少了苯酚优势吸附位点的数量,降低了吸附剂表面的异质性;吸附质间作用削弱了树脂对苯酚的吸附作用力.
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| 关 键 词： | 单宁酸 苯酚 复合功能树脂 孔堵塞机理 吸附质间作用 |
| 收稿时间： | 2009-06-25 |
| 修稿时间： | 2009-09-03 |
Competitive Adsorption of Tannic Acid and Phenol onto a Bi-functional Polymeric Adsorbent |
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| Lu,Zhaoyang,Jiang,Bicun,Li,Aimin,Wang,Xua,Ma,Yifei,Shen,Xiaopeng.Competitive Adsorption of Tannic Acid and Phenol onto a Bi-functional Polymeric Adsorbent[J].Acta Chimica Sinica,2010,68(5):437-442. |
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| Authors: | Lu Zhaoyang Jiang Bicun Li Aimin Wang Xua Ma Yifei Shen Xiaopeng |
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| Institution: | a State Key Laboratory of Pollution Control and Resource Reuse;School of the Environment;Nanjing University;Nanjing 210093;b State Environmental Protection Engineering Center of Organic Chemical Industrial Waste Water Disposal and Resources Reuse;Jiangsu N&G Environmental Science and Technology Co.Ltd.;Nanjing 210046 |
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| Abstract: | Tannic acid, a representative background compound of source water and biologically treated sewage effluent, was chosen to study the competitive effect on the adsorption of phenol by a bi-functional polymeric adsorbent.Single solute adsorption, simultaneous adsorption and preloading experiments were performed.The result indicated that tannic acid had a dramatic effect on phenol adsorption onto resin through different mechanisms, including interactions between adsorbates and pore blockage.The interaction betw... |
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| Keywords: | tannic acid phenol bi-function resin competitive adsorption pore blockage interaction between adsorbates |
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