Unexpected ligand substitutions in the cluster core {Re6Se8}: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4(O)4Cl6]3.4H2O |
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| Authors: | Yarovoi S S Mironov Y V Solodovnikov S F Naumov D Y Moroz N K Kozlova S G Simon A Fedorov V E |
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| Institution: | Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, 3, Lavrentiev Av., 630090 Novosibirsk, Russia. |
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| Abstract: | The compound Cs11(H3O)Re6Se4(O)4Cl6]3.4H2O containing a novel cluster core {Re6Se4(O)4} with ordered ligands, where the 4 positions of one face of a Se4(O)4 cube are occupied exclusively by Se atoms and 4 O atoms lie in the opposite face was synthesized via the interaction of solid Re6Se8Br2 with molten KOH. |
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