| Institution: | (1) State Scientific Research Institute “Kristall”, 6 ul. zelenaya, 606007 Dzerzhinski, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
| Abstract: | Methods for the preparation of α-azidopolynitroalkanes by reactions of polynitroalkanes or α-(difluoroamino)polynitroalkanes
with NaN3 were developed. In the case of tetranitromethane, one or two nitro groups can be substituted, depending on the reaction conditions.
The reaction of 1,1,1-trinitroethane with NaN3 affords nitro-1,2,3-triazole, together with 1-azido-1,1-dinitroethane. The IR spectra of α-azidopolynitroalkanes were studied.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 338–341, February, 1997. |
