| Biphasic Catalytic Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants |
| |
| 作者姓名： | MinLI BinXU HuaCHEN HongJieZHENG XueYuanHUANG YaoZhongLI XianJunLI |
| |
| 作者单位： | DepartmentofChemistry,SichuanUniversity,Chengdu610064 |
| |
| 摘 要： | The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB.
|
| 关 键 词： | 1-十二烯 胶体系统 阳离子型 两性离子型表面活性剂 两相催化反应 羰基化作用 铑催化剂 |
Biphasic Catalytic(Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants |
| |
| MinLI BinXU HuaCHEN HongJieZHENG XueYuanHUANG YaoZhongLI XianJunLI.Biphasic Catalytic Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants[J].Chinese Chemical Letters,2004,15(9):1022-1024. |
| |
| Authors: | Min LI Bin XU Hua CHEN Hong Jie ZHENG Xue Yuan HUANG Yao Zhong LI Xian Jun LI |
| |
| Institution: | Min LI,Bin XU,Hua CHEN,Hong Jie ZHENG,Xue Yuan HUANG,Yao Zhong LI,Xian Jun LI* Department of Chemistry,Sichuan University,Chengdu 610064 |
| |
| Abstract: | The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB. |
| |
| Keywords: | Hydroformylation gemini surfactant 1-dodecene rhodium catalyst |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
