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Reaction of [(μ-H)Os3(CO)11] anion with dioxygen |
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| Authors: | Christopher J. Cathey Brian F. G. Johnson Jack Lewis Paul R. Raithby Wing Tak Wong |
| Affiliation: | University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW UK |
| Abstract: | The anion [(μ-H)Os3(CO)11]− reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18 to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]−. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested. |
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