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Thermal and mechanical properties of epoxy resin toughened with epoxidized soybean oil
Authors:Yan Chen  Liting Yang  Jiahui Wu  Lijun Ma  David E Finlow  Shaoquan Lin  Keming Song
Institution:1. School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, People’s Republic of China
2. Exhibition Base of Production, Study & Research on New Polymer Materials and Postgraduate Students’ Innovation Training of Guangdong Higher Education Institutes, Guangzhou, People’s Republic of China
3. Guangdong Liansu Technology Co. Ltd, Shunde, Guangdong, 528318, People’s Republic of China
Abstract:A series of new modified epoxy resin (EP) cured products were prepared from epoxidized soybean oil and commercial epoxy resin, with methyl nadic anhydride as curing agent and 1-methylimidazole as promoting agent. The thermal properties of the resins were characterized by DMA and TG; DSC was used to determine the curing process. Fourier transform infrared spectroscopy was utilized to investigate their molecular structures and scanning electron microscopy was used to observe the micro morphology of their impact fracture surfaces. Tensile and impact testing was employed to characterize the mechanical properties of the cured products. The combination of commercial EP with 20 wt% ESO resulted in a bioresin with the optimum set of properties: 130.5 °C T g, 396.9 °C T 50 %, 74.89 MPa tensile strength, and 48.86 kJ m?2 impact resistance.
Keywords:
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